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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes Chen Xiao
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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes
Chen Xiao
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh) Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
138 pages
| Media | Boeken Paperback Book (Boek met zachte kaft en gelijmde rug) |
| Vrijgegeven | 20 juni 2019 |
| ISBN13 | 9783736970342 |
| Uitgevers | Cuvillier |
| Pagina's | 138 |
| Afmetingen | 148 × 210 × 8 mm · 172 g |
| Taal en grammatica | Engels |
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